Nitric Oxide Chemisorption in a Postsynthetically Modified Metal−Organic Framework
- 1 October 2009
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 48 (21), 9986-9988
- https://doi.org/10.1021/ic9015977
Abstract
Postsynthetic metal-organic framework (MOF) derivatization introduces accessible secondary amine functionalities that react with nitric oxide (NO) to form N-diazenium diolates. This is in contrast to the parent MOF that binds NO essentially irreversibly at open metal coordination sites.Keywords
This publication has 23 references indexed in Scilit:
- Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with EthylenediamineJournal of the American Chemical Society, 2009
- Post‐Synthetic Modification of Tagged Metal–Organic FrameworksAngewandte Chemie-International Edition, 2008
- “Clickable” Metal−Organic FrameworkJournal of the American Chemical Society, 2008
- Single‐Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination NetworksAngewandte Chemie-International Edition, 2008
- Crystals as Molecules: Postsynthesis Covalent Functionalization of Zeolitic Imidazolate FrameworksJournal of the American Chemical Society, 2008
- Tandem Modification of Metal–Organic Frameworks by a Postsynthetic ApproachAngewandte Chemie-International Edition, 2008
- Framework functionalisation triggers metal complex bindingChemical Communications, 2008
- Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D StructureEuropean Journal of Inorganic Chemistry, 2008
- Generation of a solid Brønsted acid site in a chiral frameworkChemical Communications, 2008
- A homochiral metal–organic porous material for enantioselective separation and catalysisNature, 2000