Improved evaluation of layer charge of n-alkylammonium-treated fine soil clays by Lorentz- and polarization-correction and curve-fitting

Abstract

The clay mineralogy of K-fixing soils from southern Germany was investigated using the alkylammonium method. Conventional X-ray diffraction chart recordings of glycerol-saturated µm samples showed peaks at 18 Å that were initially interpreted as smectites. However, step-scanning combined with the Lorentz- and polarization-correction and curve-fitting, revealed the presence of low- and high-charge smectites and of low- and high-charge vermiculites. The severe overlap of the 001 basal reflections of the high-charge vermiculites with the broad and intensive peaks of smectites sensu stricto prevented visual evaluation at the alkylchains n_c = 5–9, but this problem was overcome by curve-fitting. The 002 peaks of high-charge vermiculites (n_c = 8 and n_c = 10) in the fraction 0·1–0·2 µm could furthermore be clearly resolved from the 001 peaks of illite by curve-fitting. In one example, 003 (at n_c = 17) could be resolved from 001 of illite.