Reverse-electron-demand diels-alder dienophile π-face selectivity via conformation dependent transmission of π-σ-π electronic interactions.
- 8 July 1991
- journal article
- Published by Elsevier BV in Tetrahedron Letters
- Vol. 32 (28), 3293-3296
- https://doi.org/10.1016/s0040-4039(00)92689-3
Abstract
No abstract availableKeywords
This publication has 11 references indexed in Scilit:
- Isodicyclopentadienes and related molecules. 54. Remote electronic perturbation of .pi.-facial stereoselectivity in [4+2] cycloadditions to isodicyclopentafulvenes. The consequences of p-phenyl substitutionJournal of the American Chemical Society, 1991
- Observation of a remarkable dependence of the rate of singlet-singlet energy transfer on the configuration of the hydrocarbon bridge in bichromophoric systemsJournal of the American Chemical Society, 1990
- Electronic control of stereoselectivity. 30. X-ray analysis of the effect of apical substitution on the three-dimensional features of isodicyclopentafulvenes. Experimental demonstration of minimal bridgehead C-H angle deformation accompanying substantial hybridization change at the apical centerJournal of the American Chemical Society, 1985
- .sigma./.pi. Interaction as a controlling factor in the stereoselectivity of addition reactionsAccounts of Chemical Research, 1983
- Some aspects of orbital interactions through bonds: physical and chemical consequencesAccounts of Chemical Research, 1982
- anti‐[4 + 4]‐DicyclopentadieneAngewandte Chemie-International Edition, 1981
- Regiocontrolled hydrogenolysis of strained .sigma. bonds. Application to the synthesis of syn- and anti-tricyclo[4.2.1.12,5]decane and two elusive cyclopentadiene dimersJournal of the American Chemical Society, 1979
- Sodium-ethanol: a superior reagent for the reductive dehalogenation of polychlorinated alicyclic moleculesThe Journal of Organic Chemistry, 1979
- Effects of Through‐Bond InteractionAngewandte Chemie-International Edition, 1974
- Interaction of orbitals through space and through bondsAccounts of Chemical Research, 1971