Counter anion dependent symmetry of CuII–4-amino-1,2,4-triazole polymeric chains

Abstract

The symmetry changes and length of the symmetry independent part of [Cu(amtrz)₃]_n ²⁺ (amtrz = 4-amino-1,2,4-triazole) polymeric chains driven by different anions in crystals with BF₄ ⁻ (1), BF₄ ⁻/SiF₆ ²⁻ (2) and SiF₆ ²⁻ (3) have been studied by single crystal X-ray method.