High Frequency Faradaic Rectification Voltammetry at Microelectrodes
- 9 March 2006
- journal article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry B
- Vol. 110 (13), 6776-6784
- https://doi.org/10.1021/jp056352f
Abstract
An experimental setup for carrying out faradaic rectification measurements at micrometer-sized electrodes under potential control is described. A new method of data analysis is proposed that allows the determination of the standard rate constant and the electron-transfer coefficient of a fast charge transfer process without knowing the impedance of the microelectrode. This method is based on the frequency dependence of the shape of the faradaic rectification voltammograms (i.e., the average width of the peaks and the ratio of the peak heights) rather than on the magnitude of the faradaic rectification signal. The method was tested in the determination of heterogeneous electron transfer kinetics of Fe(CN)63-/4- and Ru(NH3)62+/3+ in aqueous solutions on a platinum microelectrode (12.5 μm in radius) and ferrocene/ferrocinum redox couple in a dimethylformamide solution on a gold microelectrode (12.5 μm in radius).Keywords
This publication has 15 references indexed in Scilit:
- Hot MicroelectrodesAnalytical Chemistry, 2002
- The ac-voltammetric study of fast charge transfer processes in benzene solutionsJournal of Electroanalytical Chemistry, 1998
- High-Frequency Impedance Spectroscopy of Platinum Ultramicroelectrodes in Flowing SolutionsAnalytical Chemistry, 1998
- Use of High-Frequency AC Voltammetry To Study Kinetics of Physical Adsorption at Mercury UltramicroelectrodesLangmuir, 1996
- Electron transfer kinetics of Fe(CN)6Journal of Electroanalytical Chemistry, 1992
- Corrosion Rate Measurement under Cathodic Polarization by Faradaic RectificationJournal of the Electrochemical Society, 1991
- Faradaic rectification: An amended treatmentElectrochimica Acta, 1967
- Faradaic Rectification and Electrode ProcessesJournal of the American Chemical Society, 1961
- Use of Faradaic Rectification for the Study of Rapid Electrode ProcessesNature, 1958
- Faradaic rectification: theory and application to the Hg2 2+/Hg electrodeTransactions of the Faraday Society, 1957