Chemical characterization of bohrium (element 107)

Abstract

The arrangement of the chemical elements in the periodic table highlights resemblances in chemical properties, which reflect the elements’ electronic structure. For the heaviest elements, however, deviations in the periodicity of chemical properties are expected^1,2,3: electrons in orbitals with a high probability density near the nucleus are accelerated by the large nuclear charges to relativistic velocities, which increase their binding energies and cause orbital contraction. This leads to more efficient screening of the nuclear charge and corresponding destabilization of the outer d and f orbitals: it is these changes that can give rise to unexpected chemical properties. The synthesis of increasingly heavy elements^4,5,6, now including that of elements 114, 116 and 118, allows the investigation of this effect, provided sufficiently long-lived isotopes for chemical characterization are available⁷. In the case of elements 104 and 105, for example, relativistic effects interrupt characteristic trends in the chemical properties of the elements constituting the corresponding columns of the periodic table⁸, whereas element 106 behaves in accordance with the expected periodicity^9,10,11,12. Here we report the chemical separation and characterization of six atoms of element 107 (bohrium, Bh), in the form of its oxychloride. We find that this compound is less volatile than the oxychlorides of the lighter elements of group VII, thus confirming relativistic calculations^{<a data-track="click" data-track-action="reference anchor" data-track-label="link" data-test="citation-ref" aria-label="Reference 13" title="Pershina, V. & Bastug, T. The electronic structure and properties of group 7 oxychlorides, MO3Cl, where M = Tc, Re, and element 107, Bh. J. Chem. Phys. 113, 1441– 1446 (2000)."...}