Rotational oscillation of two interlocked porphyrins in cerium bis(5,15-diarylporphyrinate) double-deckers

1 January 1998

journal article
research article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 10,p. 1121-1122
https://doi.org/10.1039/a801350k

Abstract

Dynamic NMR coupled with racemization studies on chiral cerium bis(5,15-diarylporphyrinate) double-deckers demonstrate that the two interlocked porphyrin ligands oscillate rotationally around the metal center.

Keywords

TWO INTERLOCKED PORPHYRINS
CHIRAL CERIUM
DECKERS DEMONSTRATE
ROTATIONAL OSCILLATION
NMR COUPLED
DYNAMIC NMR

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