Phase-matched submillimeter wave generation by difference-frequency mixing in ZnGeP2

Abstract

Using two step‐tunable CO2 lasers, we have observed phase‐matched generation of frequencies 70 <ν<110 cm−1 by nonlinear mixing in a birefringent ternary semiconductor, ZnGeP2. An observed power of ∼1.7 μW at 83.37 cm−1 gave a signal‐to‐noise ratio of ∼1000 with a Ge:Ga detector. In combination with tunable optical lasers, this technique should yield a tunable source of submillimeter waveradiation for high‐resolution spectroscopy.