Rh(I)-Catalyzed Decarboxylative Transformations of Arenecarboxylic Acids: Ligand- and Reagent-Controlled Selectivity toward Hydrodecarboxylation or Heck−Mizoroki Products
- 2 February 2010
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 12 (5), 992-995
- https://doi.org/10.1021/ol100001b
Abstract
A Rh(I)-based catalyst system has been developed to promote three types of decarboxylative transformations of arenecarboxylic acids: (1) hydrodecarboxylation, (2) Heck−Mizoroki olefination, and (3) conjugate addition. Scopes of reactions (1) and (2) were studied, and the ligand and reagent dependence of selectivity was explored.Keywords
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