One Pot Synthesis of a Polyisoprene Polyrotaxane and Conversion to a Slide-Ring Gel
- 20 October 2015
- journal article
- research article
- Published by Wiley in Macromolecular Rapid Communications
- Vol. 37 (1), 67-72
- https://doi.org/10.1002/marc.201500548
Abstract
Synthesis of a cyclodextrin (CD) polyrotaxane is achieved for the first time by simultaneous free radical polymerization of isoprene, threading by CD, and stoppering by copolymerization of styrene. This reaction is performed in an eco-friendly manner in an aqueous medium similar to classical emulsion polymerization. Threaded CD rings of the polyrotaxane are cross-linked by hexamethylene diisocyanate, leading to highly elastic slide-ring gels.Keywords
Funding Information
- Deutsche Forschungsgemeinschaft (WE 1090/17-1)
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