Convenient Synthesis of Vinyldiazomethanes from α-Diazo-β-Keto Esters and Related Systems
- 1 April 1992
- journal article
- research article
- Published by Informa UK Limited in Synthetic Communications
- Vol. 22 (7), 971-978
- https://doi.org/10.1080/00397919208019285
Abstract
A series of vinydiazomethanes were readily prepared by sodium borohydride reduction of a-diazo-p-ketoesters followed by phosphorus oxychloride induced dehydration of the resulting a-diazo-p-hydroxyesters.Keywords
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