Extraction behavior of rutherfordium into tributylphosphate from hydrochloric acid
- 1 January 2007
- journal article
- Published by Walter de Gruyter GmbH in Radiochimica Acta
- Vol. 95 (1), 1-6
- https://doi.org/10.1524/ract.2007.95.1.1
Abstract
The extraction behavior of rutherfordium (Rf) into tributylphosphate (TBP) from hydrochloric acid (HCl) has been studied together with those of the lighter group-4 elements Zr and Hf. The extractability of261Rf,169Hf, and85Zr into TBP was investigated under identical conditions in 7.2–8.0 M HCl by on-line reversed-phase extraction chromatography. The percent extractions of Rf, Hf, and Zr into the TBP resin increase steeply with increasing HCl concentration, and the order of extraction is Zr > Hf ≈ Rf. By considering the order of chloride complexation among these elements, it is suggested that the stability of the TBP complex of Rf tetrachloride is lower than those of Zr and Hf.Keywords
This publication has 13 references indexed in Scilit:
- Experimental Identification of Spin-Parities and Single-Particle Configurations inand Its-Decay DaughterPhysical Review Letters, 2005
- Chemical studies on rutherfordium (Rf) at JAERIRadiochimica Acta, 2005
- Critical evaluation of the chemical properties of the transactinide elements (IUPAC Technical Report)Published by Walter de Gruyter GmbH ,2003
- Production Cross Sections of 261Rf and 262Db in Bombardments of 248Cm with 18O and 19F IonsJournal of Nuclear and Radiochemical Sciences, 2002
- Anion-exchange Behavior of Rf in HCl and HNO3 SolutionsJournal of Nuclear and Radiochemical Sciences, 2002
- Startup of transactinide chemistry in JAERIRadiochimica Acta, 2001
- Chromatographic Study of Rutherfordium (Element 104) in the System HCl/Tributylphosphate (TBP)Radiochimica Acta, 1998
- Chemical Studies of Rutherfordium (Element 104) : Part II. Solvent Extraction into Tributylphosphate from HBr SolutionsRadiochimica Acta, 1996
- Solution Chemistry of Element 104: Part I. Liquid-Liquid Extractions with TriisooctylamineRadiochimica Acta, 1994
- Comparative solution chemistry, ionic radius, and single ion hydration energy of nobeliumInorganic Chemistry, 1974