Complexation of an amide to iridium via an iminol tautomer and evidence Ir–H ⋯ H–O hydrogen bond
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 1021-1022
- https://doi.org/10.1039/c39940001021
Abstract
The OH group of the iminol complex [IrH2L′(PPh3)2]SbF6·2H2O where L′ is the iminol tautomer of quinolin-8-acetamide, takes part in an O–H ⋯ H–Ir hydrogen bond.Keywords
This publication has 7 references indexed in Scilit:
- Facile platinum(II) promoted amide deprotonation and subsequent cyclization. Comments on a possible LmPtHNH(CO)R agostic moietyInorganica Chimica Acta, 1993
- Transition Metal Complexation of σ BondsAngewandte Chemie-International Edition, 1993
- Amide complexes of (diethylenetriamine)platinum(II)Inorganic Chemistry, 1992
- Et3NH+Co(CO)4-: hydrogen-bonded adduct or simple ion pair? Single-crystal neutron diffraction study at 15 KOrganometallics, 1992
- The role of transition metal atoms as hydrogen bond acceptors: a neutron diffraction study of [NPrn4]2[PtCl4]·cis-[PtCl2(NH2Me)2] at 20 KJ. Chem. Soc., Dalton Trans., 1991
- Concept of the H(δ+)⋯ H(δ–) interaction. A low-temperature neutron diffraction study of cis-[IrH(OH)(PMe3)4]PF6J. Chem. Soc., Dalton Trans., 1990
- Dihydrido olefin and solvento complexes of iridium and the mechanisms of olefin hydrogenation and alkane dehydrogenationJournal of the American Chemical Society, 1982