Conditions of condensate rim formation on the surface of lunar regolith particles

Abstract

Condensate objects observed in the lunar regolith are distinctly separated on the basis of morpho-logical and chemical characteristics into droplets condensed during the expansion of an impact-generated vapor cloud and films condensed on the relatively cold surface of mineral particles. Using the analyses of both condensate forms and experimental data on the evaporation of melt corresponding to a typical lunar highland rock of the gabbro-anorthosite composition from Apollo 16 sample 68415.40, the temperature conditions of vapor condensation during lunar impact events were estimated. The comparison of condensate compositions with the analyses of vapors from the evaporation experiment showed that, compared with the compositions of droplet-type condensates, the condensate rims were formed from a vapor with high contents of refractory CaO and Al₂O₃ and at very different condensation temperatures. The enrichment of vapor in CaO and Al₂O₃ could be attained only at high temperatures of melt evaporation (higher than ∼ 1850°C according to experimental data). The estimated condensation temperatures of droplets are significantly lower, ∼1750–1500°C. Rim-type condensates were produced by vapor quenching on the relatively cold surface of a solid mineral particle, which resulted in almost complete precipitation of all major components of the silicate vapor without fractionation in accordance with their individual volatilities.