A Phosphine‐Mediated Conversion of Azides into Diazo Compounds
- 10 March 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 48 (13), 2359-2363
- https://doi.org/10.1002/anie.200804689
Abstract
N2 the mild: Diazo compounds are extremely versatile intermediates for synthetic organic chemistry, but their synthesis can be challenging in the presence of delicate functional groups. The Staudinger ligation has inspired a mild method for the conversion of a broad range of azides into their diazo compound derivatives through an acyl triazene intermediate.Keywords
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