Second‐Order Nonlinear Optical Activity Induced by Ordered Dipolar Chromophores Confined in the Pores of an Anionic Metal–Organic Framework
- 18 July 2012
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 51 (42), 10542-10545
- https://doi.org/10.1002/anie.201204160
Abstract
Frequency doubling: A strategy for incorporating dipolar organic chromophores into the one-dimensional channels of an anionic metal–organic framework (MOF) has been developed to generate highly active nonlinear optical materials (see picture). The resulting MOF material shows a second-harmonic generation intensity of 18.3 versus α quartz.Keywords
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