Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
Open Access
- 21 August 2009
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 37,p. 5621-5623
- https://doi.org/10.1039/b912813a
Abstract
Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysis.Keywords
This publication has 48 references indexed in Scilit:
- Enantiomerically Pure Titanium Complexes Containing an [OSSO]‐Type Bis(phenolate) Ligand: Synthesis, Structure, and Formation of Optically Active OligostyrenesChemistry – An Asian Journal, 2008
- When Single-Site Polymerization Catalysis Meets Chirality: Optical Activity of Stereoregular PolyolefinsAngewandte Chemie-International Edition, 2007
- Stereospecific Styrene Enchainment at a Titanium Site within a Helical Ligand Framework: Evidence for the Formation of Homochiral PolystyreneAngewandte Chemie-International Edition, 2007
- Empirical Description of Chiral AutocatalysisThe Journal of Physical Chemistry A, 2006
- Chiral Discrimination of Cryptochiral Saturated Quaternary and Tertiary Hydrocarbons by Asymmetric AutocatalysisJournal of the American Chemical Society, 2006
- Highly enantioselective asymmetric autocatalysis of 2‐alkenyl‐ and 2‐vinyl‐5‐pyrimidyl alkanols with significant amplification of enantiomeric excessChirality, 2002
- d- and l-Quartz-Promoted Highly Enantioselective Synthesis of a Chiral Organic CompoundJournal of the American Chemical Society, 1999
- Practically Perfect Asymmetric Autocatalysis with (2-Alkynyl-5-pyrimidyl)alkanolsAngewandte Chemie-International Edition, 1999
- The road to chiral amplification in polymers originated in ItalyChirality, 1997
- Asymmetric hydrooligomerization of propyleneJournal of the American Chemical Society, 1987