Single Nanoparticle Tracking Reveals Influence of Chemical Functionality of Nanoparticles on Local Ordering of Liquid Crystals and Nanoparticle Diffusion Coefficients
- 21 May 2009
- journal article
- Published by American Chemical Society (ACS) in Nano Letters
- Vol. 9 (7), 2794-2801
- https://doi.org/10.1021/nl901498d
Abstract
This letter reports that darkfield microscopy can be used to track the trajectories of chemically functionalized gold nanoparticles in nematic liquid crystals (LCs), thus leading to measurements of the diffusion coefficients of the nanoparticles in the LCs. These measurements reveal that the diffusion coefficients of the nanoparticles dispersed in the LC are strongly dependent on the surface chemistry of the nanoparticles. Because the changes in surface chemistry are measured to have negligible influence on the diffusion coefficients of the same nanoparticles dispersed in isotropic solvents, we conclude that surface chemistry-induced changes in the local order of LCs underlie the behavior of the diffusion coefficients of the nanoparticles in the LC. Surface chemistry-dependent ordering of the LCs near the surfaces of the nanoparticles was also found to influence diffusion coefficients measured when the LC was heated above the bulk nematic-to-isotropic transition temperature. These experimental measurements are placed into the context of past theoretical predictions regarding the impact of local ordering of LCs on diffusion coefficients. The results that emerge from this study provide important insights into the mobility of nanoparticles in LCs and suggest new approaches based on measurements of nanoparticle dynamics that can yield information on the ordering of LCs near nanoparticles.This publication has 72 references indexed in Scilit:
- Assembly of Gold Nanoparticles into Microwire Networks Induced by Drying Liquid BridgesPhysical Review Letters, 2009
- Self-Assembly of Colloids with Liquid ProtrusionsJournal of the American Chemical Society, 2008
- Self-Organized Silver Nanoparticles for Three-Dimensional Plasmonic CrystalsNano Letters, 2008
- Direct and Stepwise Energy Transfer from Excitons to Plasmons in Close-Packed Metal and Semiconductor Nanoparticle Monolayer FilmsPhysical Review Letters, 2008
- Electron Hopping Dynamics in Au38 Nanoparticle Langmuir Monolayers at the Air/Water InterfaceJournal of the American Chemical Society, 2006
- Gold Nanoparticle Networks with Photoresponsive Interparticle SpacingsLangmuir, 2005
- Effects of the Surface Pressure on the Formation of Langmuir−Blodgett Monolayer of NanoparticlesLangmuir, 2004
- Colloidal crystal templating of three-dimensionally ordered macroporous solids: materials for photonics and beyondCurrent Opinion in Solid State and Materials Science, 2001
- Excimer Laser Recrystallization of Selectively Floating a-Si Active Layer for Large-Grained Poly-Si FilmMRS Proceedings, 2001
- Structured Porous Materials via Colloidal Crystal Templating: From Inorganic Oxides to MetalsAdvanced Materials, 2000