Combination of orthogonal supramolecular interactions in polymeric architectures

Abstract

Supramolecular polymers represent a highly interesting approach towards new “smart materials”. A recent strategy includes the combination of different “orthogonal” non-covalent binding sites within one polymer system. Different functionalities can be introduced in a highly defined way by controlled self-assembly processes. This feature article presents highlights in the supramolecular polymer chemistry of multiple hydrogen-bonding, metal complexation (especially of bi- and terpyridines) and host–guest interactions as well as recent advances in combining these interactions in novel polymers.