Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’[Ru(η⁵-C₇H₁₁)₂H][BF₄]

1 January 1988

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 14,p. 951-953
https://doi.org/10.1039/c39880000951

Abstract

Chloride extraction from [Ru(η³ : η³-C₁₀H₁₆)Cl₂]₂ or [Ru(η³ : η³-C₁₀H₁₆)Cl₂L][L = P(OMe)₃ or Bu^tNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η⁵-C₇H₁₁)₂H][BF₄].

Keywords

PROTONATED
ORGANORUTHENIUM
OPEN METALLOCENE
SUP
DIMETHYLOCTADIENEDIYL

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Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4]

Abstract

Keywords

Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’[Ru(η⁵-C₇H₁₁)₂H][BF₄]