Mesoporous hybrid materials containing two transition metal ions, one in the framework, the other in the channel pores
- 3 June 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1564-1565
- https://doi.org/10.1039/b303492p
Abstract
Mesoporous hybrid materials containing bridged metal–cyclam moieties in the silicate framework were synthesized by using triblock copolymer F127 as template and SiH3 as hydrolysable terminal groups; grafting of a metal–cyclam precursor in the channel pores led to materials containing two different strongly chelated transition metal ions in two steps.Keywords
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