Time-Resolved Resonance Raman Observation of the 2-Fluorenylnitrenium Ion Reaction with Guanosine to Form a C8 Intermediate
- 17 May 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (23), 8246-8247
- https://doi.org/10.1021/ja0505651
Abstract
Time-resolved resonance Raman spectroscopy was used to directly observe the reaction of the 2-fluorenylnitrenium ion with guanosine to produce a C8 intermediate species. Comparison of the Raman spectra with results of density functional theory calculations indicates the C8 intermediate forms two CN conjugated bonds in ring 1 of the guanosine moiety.Keywords
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