Composition‐Graded Cesium Lead Halide Perovskite Nanowires with Tunable Dual‐Color Lasing Performance
- 21 May 2018
- journal article
- research article
- Published by Wiley in Advanced Materials
- Vol. 30 (27), e1800596
- https://doi.org/10.1002/adma.201800596
Abstract
Cesium lead halide (CsPbX3) perovskite has emerged as a promising low‐threshold multicolor laser material; however, realizing wavelength‐tunable lasing output from a single CsPbX3 nanostructure is still constrained by integrating different composition. Here, the direct synthesis of composition‐graded CsPbBrxI3−x nanowires (NWs) is reported through vapor‐phase epitaxial growth on mica. The graded composition along the NW, with an increased Br/I from the center to the ends, comes from desynchronized deposition of cesium lead halides and temperature‐controlled anion‐exchange reaction. The graded composition results in varied bandgaps along the NW, which induce a blueshifted emission from the center to the ends. As an efficient gain media, the nanowire exerts position‐dependent lasing performance, with a different color at the ends and center respectively above the threshold. Meanwhile, dual‐color lasing with a wavelength separation of 35 nm is activated simultaneously at a site with an intermediate composition. This position‐dependent dual‐color lasing from a single nanowire makes these metal halide perovskites promising for applications in nanoscale optical devices.Funding Information
- National Natural Science Foundation of China (21425101, 21461162001, 21621061, 21590791)
- Ministry of Science and Technology of the People's Republic of China (2014CB643803, 2017YFA0205101)
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