The enhanced ferroelectricity in Sr1-δTiO3/BaTiO3 superlattices with Sr deficiency
- 29 July 2020
- journal article
- research article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 53 (31), 314004
- https://doi.org/10.1088/1361-6463/ab8990
Abstract
Here we report the tunable ferroelectricity in superlattices of (Sr1-delta TiO3)(n)/(BaTiO3)(8) with delta & x224d; 5% and the maximally enhanced ferroelectricity is found in the n= 6 superlattice. The room-temperature remnant polarization of n =6 is enhanced by 70% and 1120% compared to those of BaTiO3 and Sr1-delta TiO3 thin films, respectively. The ferroelectric transition temperature of n =6 is 40 K higher than that of the BaTiO3 film, and is independent of the measurement frequency. The dependence of remnant field 2P(r) on n coincides well with the n dependence of gamma/alpha, which is ratio between out-of-plane and in-plane octahedral rotation angles. It thus suggests a strong correlation between the octahedral rotation pattern and the ferroelectric distortion. Our study demonstrates the importance of constructing superlattices to enhance the ferroelectric properties of the defect-engineered materials to be better than the pristine materials.Funding Information
- Fundamental Research Funds for the Central Universities (No. WK2340000088)
- National Natural Science Foundation of China (No. 51627901 and No. 11574287)
- the youth innovation promotion association cas (No. 2016389)
- National Key Research and Development Program of China (No. 2016YFA0401004)
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