Preparation of Yellow Fluorescent N,O-CDs and its Application in Detection of ClO−

Abstract

Accurate and efficient detection of ClO⁻ was extremely important due to the harm of ROS in the environment and organism. In this paper, yellow fluorescent N,O-CDs were successfully prepared by the solvothermal method. The microscopic size of the N,O-CDs was approximately spherical with an average particle size of 4.8 ± 0.8 nm. The fluorescence quantum yield in ethanol solution was calculated as 10.5 % using fluorescein as the standard reference. The as-fabricated N,O-CDs had high sensitivity and low detection limit (7.5 µM) for quantitatively detecting ClO⁻ with a linear range from 0.07 mM to 0.16 mM. The probe not only shows good selectivity and anti-interference to metal ions, anions and amino acids but also has excellent light stability and thermal stability. Also, a wide selection range for pH was demonstrated. Graphical Abstract