Thiolate-based One-dimensional Flexible Pb–MOFs Exhibiting a Large Sorption Hysteresis Phenomenon
- 5 May 2021
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 50 (5), 1053-1056
- https://doi.org/10.1246/cl.210054
Abstract
A novel thiolate-based Pb-metal-organic framework, [Pb2(Hdtd)4·2DMSO]n (KGF-2·DMSO, H2dtd = 6-dibutylamino-1,3,5-triazine-2,4-dithol and DMSO = dimethyl sulfoxide) was prepared. The crystal structure of KGF-2·DMSO consists of a one-dimensional chain composed of Pb ions and surrounding ligands. Following removal of the guest DMSO molecules, KGF-2 was obtained as a crystalline powder, which exhibited selective water sorption properties.Keywords
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