Stabilizing sulfur vacancy defects by performing “click” chemistry of ultrafine palladium to trigger a high-efficiency hydrogen evolution of MoS2
- 17 April 2020
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Nanoscale
- Vol. 12 (18), 9943-9949
- https://doi.org/10.1039/d0nr01693d
Abstract
Defect engineering is widely applied in transition metal dichalcogenides to produce high-purity hydrogen. However, the instability of vacancy states on catalysis still remains a considerable challenge. Here, our first-principles calculations showed that, by optimizing the asymmetric S vacancy in the highly asymmetric 1T′ crystal of layered bitransition metal dichalcogenides (Co–MoS2) in light of Pd modulation, the relative amount of metastable phase and the quantity of active sites in the structure can be reduced and increased, respectively, leading to a further boosted hydrogen evolution reaction (HER) activity toward layered bi-transition metal dichalcogenides. Thus, we then used a “click” chemistry strategy to make such a catalyst with engineered unsaturated sulfur edges via a strong coupling effect between ultrafine Pd ensembles and Co–MoS2 nanosheets. As expected, the Pd-modulated Co–MoS2 nanosheets exhibited a very low overpotential of 60 mV at 10 mA cm−2 with a small Tafel slope (56 mV dec−1) for the HER in 1.0 M PBS, comparable to those of commercial Pt/C. In addition, their high HER activity was retained in acidic and alkaline conditions. Both the theoretical and experimental results revealed that Pd ensembles can efficiently activate and stabilize the inert basal plane S sites during HER processes as a result of the formation of Pd–S in Co–MoS2. This work not only provides a deeper understanding of the correlation between defect sites and intrinsic HER catalytic properties for transition metal chalcogenide (TMD)-based catalysts, but also offers new insights into better designing earth-abundant HER catalysts displaying high efficiency and durability.Funding Information
- National Natural Science Foundation of China (21501096)
- Natural Science Foundation of Jiangsu Province (BK20150086)
- Jiangsu Provincial Department of Education (15KJB150020)
- Six Talent Peaks Project in Jiangsu Province (JY-087)
- Program for Jiangsu Excellent Scientific and Technological Innovation Team
- Nanjing Xiaozhuang University (2019NXY20)
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