A Novel Composite Membrane from QPSU and SiO2for Solid Alkaline Fuel Cell Applications
- 10 December 2012
- journal article
- research article
- Published by Taylor & Francis Ltd in International Journal of Green Energy
- Vol. 12 (7), 756-765
- https://doi.org/10.1080/15435075.2012.738449
Abstract
The goal of this work is to develop a novel composite membrane from quaternized polysulfone (QPSU) and silica (SiO2), to fabricate alkaline membrane electrode assemblies (MEAs) and to subsequently test the MEAs in 5 cm × 5 cm single cell configuration using Pt/C and Ag/C as anode and cathode catalysts, respectively. The composite membranes were characterized in terms of water absorption, ion exchange capacity and ionic conductivity. The physicochemical studies Fourier transform infra red (FT-IR), thermogravimetric analysis (TGA), X-ray diffraction (XRD) studies, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and universal testing machine (UTM) were used to investigate the relation between the structure and performance of the composite membranes. The results show that the SiO2 was compatible with the QPSU membrane. The thermal stability and ionic conductivity of the QPSU/SiO2 composite membranes were higher than that of quaternized polysulfone (QPSU) membrane. The maximum performance was achieved for 10 wt.% SiO2 with power density of 149.6 mW/cm2 at current density of 440 mA/cm2.Keywords
Funding Information
- Department of Scince and Tchnology, New Delhi, India (SR/S2/CMP-06/2008)
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