Nitroprusside as a promising building block to assemble an organic-inorganic hybrid for thermo-responsive switching materials
- 21 May 2020
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 56 (41), 5488-5491
- https://doi.org/10.1039/d0cc01877e
Abstract
We present a new hybrid compound, namely (Me2NH2)[KFe(CN)(5)(NO)], possessing a unique nitroprusside-based inorganic host framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds and synchronously deformed inorganic framework give rise to thermal-responsive switching behaviours on both thermal expansion and nonlinear optical properties during the phase transition at around room temperature.Funding Information
- National Natural Science Foundation of China (21722107, 21671202, 21805312, 21821003)
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