Arrayed Cobalt Phosphide Electrocatalyst Achieves Low Energy Consumption and Persistent H2Liberation from Anodic Chemical Conversion
Open Access
- 22 July 2020
- journal article
- research article
- Published by Springer Science and Business Media LLC in Nano-Micro Letters
- Vol. 12 (1), 1-14
- https://doi.org/10.1007/s40820-020-00486-2
Abstract
Electrochemical reduction of water to hydrogen (H-2) offers a promising strategy for production of clean energy, but the design and optimization of electrochemical apparatus present challenges in terms of H(2)recovery and energy consumption. Using cobalt phosphide nanoarrays (Co2P/CoP NAs) as a charge mediator, we effectively separated the H(2)and O(2)evolution of alkaline water electrolysis in time, thereby achieving a membrane-free pathway for H(2)purification. The hierarchical array structure and synergistic optimization of the electronic configuration of metallic Co2P and metalloid CoP make the Co2P/CoP NAs high-efficiency bifunctional electrocatalysts for both charge storage and hydrogen evolution. Theoretical investigations revealed that the introduction of Co2P into CoP leads to a moderate hydrogen adsorption free energy and low water dissociation barrier, which are beneficial for boosting HER activity. Meanwhile, Co2P/CoP NAs with high capacitance could maintain a cathodic H(2)evolution time of 1500 s at 10 mA cm(-2)driven by a low average voltage of 1.38 V. Alternatively, the energy stored in the mediator could be exhausted via coupling with the anodic oxidation of ammonia, whereby only 0.21 V was required to hold the current for 1188 s. This membrane-free architecture demonstrates the potential for developing hydrogen purification technology at low cost.This publication has 49 references indexed in Scilit:
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