High transference number enabled by sulfated zirconia superacid for lithium metal batteries with carbonate electrolytes
- 9 February 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Energy & Environmental Science
- Vol. 14 (3), 1420-1428
- https://doi.org/10.1039/d0ee03967e
Abstract
The prospect of increasing the energy density has promoted research on lithium metal batteries. Yet, avoiding the uncontrolled growth of lithium dendrites and the resulting interfacial instability to ensure the practical viability of the given battery technology remains a considerable challenge. Here, we report coating the separator with sulfated zirconia superacid to achieve a high lithium ion transference number of 0.85 and excellent cycle life when a full-cell paired with a LiNi0.82Co0.07Mn0.11O2 cathode was tested in a carbonate electrolyte under practical operating conditions. The exceptionally high transference number is attributed to strengthened binding of the PF6 − anion of the lithium salt with the superacid. Furthermore, the presence of the superacid induces a mechanically stable solid–electrolyte-interphase (SEI) layer rich in LixPOyFz. This study demonstrates the beneficial effect of the superacid on emerging post-lithium-ion batteries by immobilizing the anion of the salt as well as modifying the SEI composition.Funding Information
- National Research Foundation of Korea (NRF-2018M1A2A2063340, NRF-2018M1A2A2063353, NRF-2021R1A2B5B03001956)
- Korea Institute for Advancement of Technology
- Ministry of Trade, Industry and Energy (S2483103)
This publication has 51 references indexed in Scilit:
- Quantifying inactive lithium in lithium metal batteriesNature, 2019
- The Synergistic Effect of Cation and Anion of an Ionic Liquid Additive for Lithium Metal AnodesAdvanced Energy Materials, 2018
- Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteriesNature Energy, 2017
- Designing Artificial Solid-Electrolyte Interphases for Single-Ion and High-Efficiency Transport in BatteriesJoule, 2017
- A facile surface chemistry route to a stabilized lithium metal anodeNature Energy, 2017
- Reviving Lithium‐Metal Anodes for Next‐Generation High‐Energy BatteriesAdvanced Materials, 2017
- Extending the Life of Lithium‐Based Rechargeable Batteries by Reaction of Lithium Dendrites with a Novel Silica Nanoparticle Sandwiched SeparatorAdvanced Materials, 2016
- Transition of lithium growth mechanisms in liquid electrolytesEnergy & Environmental Science, 2016
- Promise and reality of post-lithium-ion batteries with high energy densitiesNature Reviews Materials, 2016
- Electrical Energy Storage for the Grid: A Battery of ChoicesScience, 2011