Direct Dynamic Evidence of Charge Separation in a Dye‐Sensitized Solar Cell Obtained under Operando Conditions by Raman Spectroscopy
- 13 March 2020
- journal article
- research article
- Published by Wiley in Angewandte Chemie
- Vol. 59 (27), 10780-10784
- https://doi.org/10.1002/anie.201915824
Abstract
Interfaces play an important role in enhancing the energy conversion performance of dye‐sensitized solar cells (DSCs). The interface effects have been studied by many techniques, but almost all studies only performed on a portion of DSC, rather than on a complete solar cell. Hence, monitoring the interface evolution of a DSC is still very challenging. Here, in situ/operando resonance Raman (RR) spectroscopic analyses were carried out to monitor the dynamic observations of the photovoltaic conversion process from a DSC. We observed the creation of new species (i.e., polyiodide and iodine aggregates) in the photosensitization process. We also successfully identified molecular‐scale dynamic evidence that the bands from the C=C of 2,2'‐bipyridyl (bpy), the S=C=N of NCS ligand and photochemical products show reasonably strong intensity and frequency changes, which clearly demonstrates that they are important pathways of charge separation. Furthermore, RR spectroscopy also be applicable to quickly evaluate the performance of DSCs.Funding Information
- National Natural Science Foundation of China (21503021, 21773080, 21773079, 21974054)
- National Research Foundation of Korea (NRF-2018R1A2A3074587)
This publication has 29 references indexed in Scilit:
- Stabilizing halide perovskite surfaces for solar cell operation with wide-bandgap lead oxysaltsScience, 2019
- Planar perovskite solar cells with long-term stability using ionic liquid additivesNature, 2019
- Controlling Interfacial Charge Transfer and Fill Factors in CuO‐based Tandem Dye‐Sensitized Solar CellsAngewandte Chemie, 2018
- Steuerung des Grenzflächen‐Ladungstransfers und des Fill‐Factors in CuO‐basierten Grätzel‐TandemzellenAngewandte Chemie, 2018
- In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfacesNature Energy, 2018
- Direct Contact of Selective Charge Extraction Layers Enables High-Efficiency Molecular PhotovoltaicsJoule, 2018
- Recent progress and utilization of natural pigments in dye sensitized solar cells: A reviewRenewable and Sustainable Energy Reviews, 2017
- An overview of the Challenges in the commercialization of dye sensitized solar cellsRenewable and Sustainable Energy Reviews, 2017
- Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizersNature Chemistry, 2014
- Materials interface engineering for solution-processed photovoltaicsNature, 2012