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Open questions on the reactivity of Criegee intermediates

Communications Chemistry , Volume 4, pp 1-4; doi:10.1038/s42004-021-00483-5

Abstract: Criegee intermediates are reactive intermediates formed in Earth’s atmosphere through ozonolysis of alkenes. Here the authors outline the fundamental chemistry that influences their highly conformer- and substituent-dependent unimolecular and bimolecular reactivity, and discuss open questions of fundamental and atmospheric interest.
Keywords: authors outline / Criegee / atmospheric interest / fundamental chemistry / dependent unimolecular / discuss open / highly conformer / intermediates formed / substituent dependent

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