Construction of Heptagon‐Containing Molecular Nanocarbons
Top Cited Papers
- 5 February 2021
- journal article
- review article
- Published by Wiley in Angewandte Chemie
- Vol. 60 (44), 23508-23532
- https://doi.org/10.1002/anie.202100260
Abstract
Molecular nanocarbons containing heptagonal rings have attracted increasing interest due to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing. Heptagon incorporation can not only induce negative curvature within nanocarbon scaffolds, but also confer significantly altered properties through interaction with adjacent non‐hexagonal rings. Despite the disclosure of several beautiful examples in recent years, synthetic strategies toward heptagon‐embedded molecular nanocarbons remain relatively limited due to the intrinsic challenges of heptagon formation and incorporation into polyarene frameworks. In this minireview, recent advances in solution‐mediated and surface‐assisted synthesis of heptagon‐embedded molecular nanocarbons, as well as the intriguing properties of these frameworks, will be discussed.Keywords
Funding Information
- Japan Society for the Promotion of Science (JP19H05463, JP18H02019, JP20K21192)
- Japan Science and Technology Agency (JPMJER1302, JPMJCR19R1)
This publication has 211 references indexed in Scilit:
- Comparison of Oxidative Aromatic Coupling and the Scholl ReactionAngewandte Chemie, 2013
- A grossly warped nanographene and the consequences of multiple odd-membered-ring defectsNature Chemistry, 2013
- Facile Bucky‐Bowl Synthesis by Regiospecific Cove‐Region Closure by HF EliminationAngewandte Chemie, 2012
- Facile Bucky‐Bowl Synthesis by Regiospecific Cove‐Region Closure by HF EliminationAngewandte Chemie, 2012
- Indeno[1,2‐b]fluorenes: Fully Conjugated Antiaromatic Analogues of AcenesAngewandte Chemie, 2010
- Indeno[1,2‐b]fluorenes: Fully Conjugated Antiaromatic Analogues of AcenesAngewandte Chemie, 2010
- Photochemical Oxidative Cyclisation of Stilbenes and Stilbenoids—The Mallory-ReactionMolecules, 2010
- Photoswitchable Tetraethynylethene-Dihydroazulene ChromophoresHelvetica Chimica Acta, 2001
- From Hexa‐peri‐hexabenzocoronene to “Superacenes”Angewandte Chemie, 1997
- Synthesis of Dipleiadiene by “Serendipity”Angewandte Chemie, 1985