15.9% organic tandem solar cell with extended near-infrared absorption
Open Access
- 13 April 2020
- journal article
- research article
- Published by AIP Publishing in Applied Physics Letters
- Vol. 116 (15), 153501
- https://doi.org/10.1063/5.0005172
Abstract
Stacking single-junction organic solar cells is effective in increasing the power conversion efficiency (PCE) by reducing the thermalization loss and increasing the open circuit voltage. Recent developments of non-fullerene acceptors (NFAs) offer a range of materials whose energy gaps are suited for absorbing relatively narrow slices of the solar spectrum, thus easing requirements for current balance between sub-elements in multijunction stacks. Here, we demonstrate a solution-processed tandem organic solar cell comprising a binary, visible-absorbing sub-cell and a ternary near-infrared (NIR) absorbing sub-cell. The ternary NIR sub-cell utilizes a narrow energy gap NFA that enables a broadened and increased absorption compared to a binary NIR sub-cell. An isopropanol surface treatment is developed to connect the hydrophilic–hydrophobic surfaces in the charge recombination zone (CRZ) located between the sub-cells. The nearly optically and electrically lossless CRZ combined with an anti-reflection coating results in tandem organic photovoltaics with PCE = 15.9% ± 0.2% under AM 1.5G simulated illumination.Funding Information
- Collaborative Innovation Centre of Suzhou Science and Technology
- “111” Project of the State Administration of Foreign Experts Affairs of China
- U.S. Department of Energy (DE-EE0008561)
- Office of Naval Research (N00014-17-1-2211)
- Foundation for Innovative Research Groups of the National Natural Science Foundation of China (21871199)
- Universal Display Corporation
This publication has 25 references indexed in Scilit:
- Enhanced Light Utilization in Semitransparent Organic Photovoltaics Using an Optical Outcoupling ArchitectureAdvanced Materials, 2019
- Advances in Solution‐Processed Multijunction Organic Solar CellsAdvanced Materials, 2018
- Near‐Infrared Ternary Tandem Solar CellsAdvanced Materials, 2018
- Continuous roll-to-roll fabrication of organic photovoltaic cells via interconnected high-vacuum and low-pressure organic vapor phase deposition systemsApplied Physics Letters, 2018
- Metal‐Organic Framework‐Derived Carbons for Battery ApplicationsAdvanced Energy Materials, 2018
- High fabrication yield organic tandem photovoltaics combining vacuum- and solution-processed subcells with 15% efficiencyNature Energy, 2018
- High Efficiency Near-Infrared and Semitransparent Non-Fullerene Acceptor Organic Photovoltaic CellsJournal of the American Chemical Society, 2017
- High‐Efficiency, Vacuum‐Deposited, Small‐Molecule Organic Tandem and Triple‐Junction Photovoltaic CellsAdvanced Energy Materials, 2014
- Optimizing Polymer Tandem Solar CellsAdvanced Materials, 2010
- Double and triple junction polymer solar cells processed from solutionApplied Physics Letters, 2007