The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction

Abstract
We demonstrate here the suitability of CsPbBr3 nanoparticles as photosensitizers for a demanding photoredox catalytic homo- and cross-coupling of alkyl bromides at room temperature by merely using visible light and an electron donor, thanks to the cooperative action between the nanoparticle surface and organic capping.
Funding Information
  • Generalitat Valenciana (IDIFEDER/2018/064, PROMETEO/2019/080)
  • H2020 European Research Council (FP7-PEOPLE-2010-ERG-268445)
  • Ministerio de Economía y Competitividad (CTQ2016-80038-R, CTQ2017-82711-P, FPU17/ 05564, FPU14/02550)