The synergy between the CsPbBr3 nanoparticle surface and the organic ligand becomes manifest in a demanding carbon–carbon coupling reaction
- 25 March 2020
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 56 (37), 5026-5029
- https://doi.org/10.1039/d0cc01339k
Abstract
We demonstrate here the suitability of CsPbBr3 nanoparticles as photosensitizers for a demanding photoredox catalytic homo- and cross-coupling of alkyl bromides at room temperature by merely using visible light and an electron donor, thanks to the cooperative action between the nanoparticle surface and organic capping.Keywords
Funding Information
- Generalitat Valenciana (IDIFEDER/2018/064, PROMETEO/2019/080)
- H2020 European Research Council (FP7-PEOPLE-2010-ERG-268445)
- Ministerio de Economía y Competitividad (CTQ2016-80038-R, CTQ2017-82711-P, FPU17/ 05564, FPU14/02550)
This publication has 43 references indexed in Scilit:
- Brightly Luminescent and Color-Tunable Colloidal CH3NH3PbX3 (X = Br, I, Cl) Quantum Dots: Potential Alternatives for Display TechnologyACS Nano, 2015
- Assessing capability of semiconductors to split water using ionization potentials and electron affinities onlyPhysical Chemistry Chemical Physics, 2013
- Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide PerovskitesScience, 2012
- Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%Scientific Reports, 2012
- High performance aniline vapor detection based on multi-branched fluorescent triphenylamine-benzothiadiazole derivatives: branch effect and aggregation control of the sensing performanceJournal of Materials Chemistry, 2012
- Metal‐Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible LightAngewandte Chemie, 2010
- Metallfreie kooperative asymmetrische Organophotoredoxkatalyse mit sichtbarem LichtAngewandte Chemie, 2010
- Enantioselective α-Benzylation of Aldehydes via Photoredox OrganocatalysisJournal of the American Chemical Society, 2010
- Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic CellsJournal of the American Chemical Society, 2009
- Carbanion and Radical Intermediacy in the Electrochemical Reduction of Benzyl Halides in AcetonitrileJournal of the Electrochemical Society, 1987