Conductive, Large-Area, and Continuous 7,7,8,8-Tetracyanoquinodimethane@HKUST-1 Thin Films Fabricated Using Solution Shearing
- 19 February 2021
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 13 (8), 10202-10209
- https://doi.org/10.1021/acsami.1c00640
Abstract
Most metal–organic frameworks (MOFs) have an insulating nature due to their porosity and redox-inactive organic components. The electrical conductivity of the prototypical MOF, HKUST-1, can be tuned by infiltrating a small-molecule organic semiconductor, 7,7,8,8-tetracyanoquinodimethane (TCNQ), into the HKUST-1 pores, creating [email protected] However, current processes of creating [email protected] films have many roadblocks such as slow crystallization rates, which limit high throughput production, and the formation of Cu(TCNQ) as a byproduct, which affects the electrical conductivity and degrades the chemical structure of HKUST-1. In this work, we show that HKUST-1 films can be rapidly synthesized over large areas with consistent thickness and no pinholes via a meniscus-guided coating technique called solution shearing. The subsequent pore activation process and TCNQ impregnation can be completed via solvent exchange to minimize the formation of the Cu(TCNQ) byproduct, and we obtain an increase in electrical conductivity of the solution-sheared [email protected] thin films of over 7 orders of magnitude, reaching a maximum value of 2.42 × 10–2 S m–1 when TCNQ is incorporated for 10 days. The conductivity of solution-sheared [email protected] is higher compared to films formed by high-pressure pelletization of [email protected] We show that solution shearing can produce large-area thin films rapidly and reduce the formation of grain boundaries better than pelletization, allowing for large-area electronics with both charge transport and porosity for applications as sensors and electronics.Funding Information
- Ivy Foundation
This publication has 44 references indexed in Scilit:
- The Chemistry and Applications of Metal-Organic FrameworksScience, 2013
- Look fast: Crystallization of conjugated molecules during solution shearing probed in‐situ and in real time by X‐ray scatteringPhysica Status Solidi (RRL) – Rapid Research Letters, 2012
- Introduction to Metal–Organic FrameworksChemical Reviews, 2012
- Metal–Organic Framework Thin Films: From Fundamentals to Applications.Chemical Reviews, 2011
- Ultrahigh Porosity in Metal-Organic FrameworksScience, 2010
- Direct Patterning of Oriented Metal–Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor SolutionsAdvanced Materials, 2010
- From Convective Assembly to Landau−Levich Deposition of Multilayered Phospholipid Films of Controlled ThicknessLangmuir, 2009
- Selective Nucleation and Growth of Metal−Organic Open Framework Thin Films on Patterned COOH/CF3-Terminated Self-Assembled Monolayers on Au(111)Journal of the American Chemical Society, 2005
- Ordered porous materials for emerging applicationsNature, 2002
- A Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ]
n
Science, 1999