Recent strategies to improve the photoactivity of metal–organic frameworks
- 8 January 2021
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 50 (7), 2342-2349
- https://doi.org/10.1039/d0dt03844j
Abstract
Metal-organic frameworks (MOFs) are micro/mesoporous crystalline materials with high surface area, tunability, and compositional diversity which have been widely applied in diverse applications, including catalysis. The rigid framework built from organic and inorganic functional structures can offer the merits of both, providing a platform to convert solar energy into usable or storable energy. Various approaches such as bandgap engineering, modulating charge separation and increasing intrinsic activity have been developed to improve the photocatalytic performance. This frontier article summarizes the current state-of-the-art in the use of MOFs as photocatalysts, emphasizing the recent strategies to optimize their visible-light-driven catalytic activities. Hopefully, this review could foreshadow new guidelines for explaining the current interest in exploiting novel MOF-based photocatalysts.Keywords
Funding Information
- Natural Science Foundation of Zhejiang Province (LY20E020001)
- National Natural Science Foundation of China (51672251)
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