Nanoporous Metal Phosphonate Hybrid Materials as a Novel Platform for Emerging Applications: A Critical Review
- 19 February 2021
- Vol. 17 (22), 2005304
- https://doi.org/10.1002/smll.202005304
Abstract
Nanoporous metal phosphonates are propelling the rapid development of emerging energy storage, catalysis, environmental intervention, and biology, the performances of which touch many fundamental aspects of portable electronics, convenient transportation, and sustainable energy conversion systems. Recent years have witnessed tremendous research breakthroughs in these fields in terms of the fascinating pore properties, the structural periodicity, and versatile skeletons of porous metal phosphonates. This review presents recent milestones of porous metal phosphonate research, from the diversified synthesis strategies for controllable pore structures, to several important applications including adsorption and separation, energy conversion and storage, heterogeneous catalysis, membrane engineering, and biomaterials. Highlights of porous structure design for metal phosphonates are described throughout the review and the current challenges and perspectives for future research in this field are discussed at the end. The aim is to provide some guidance for the rational preparation of porous metal phosphonate materials and promote further applications to meet the urgent demands in emerging applications.Funding Information
- National Natural Science Foundation of China (21573115, 21875118)
- Natural Science Foundation of Tianjin City (19JCZDJC37700)
- Northern Kentucky University
- Natural Science Foundation of Tianjin City (19JCZDJC37700)
This publication has 192 references indexed in Scilit:
- Self-assembled hybrid tinphosphonate nanoparticles with bimodal porosity: an insight towards the efficient and selective catalytic process for the synthesis of bioactive 1,4-dihydropyridines under solvent-free conditionsJournal of Materials Chemistry A, 2013
- Crystal transformation synthesis of a highly stable phosphonate MOF for selective adsorption of CO2CrystEngComm, 2013
- Mesoporous phosphonate–TiO2 nanoparticles for simultaneous bioresponsive sensing and controlled drug releaseThe Analyst, 2012
- Organic–inorganic hybrid tinphosphonate material with mesoscopic void spaces: an excellent catalyst for the radical polymerization of styreneCatalysis Science & Technology, 2012
- Microemulsion Approach to Non‐Agglomerated and Crystalline NanomaterialsAdvanced Functional Materials, 2008
- Preparation, Characterizaton, and Catalytic Aerobic Oxidation by a Vanadium Phosphonate Mesoporous Material Constructed from a Dendritic TetraphosphonateChemistry of Materials, 2006
- New Preparation Methods for Composite Membranes for Medium Temperature Fuel Cells Based on Precursor Solutions of Insoluble Inorganic CompoundsFuel Cells, 2005
- Functionalization of Aluminophosphate AlPO4-H1 (VPI-5) with Phenylphosphonic AcidChemistry of Materials, 2004
- Preparation, characterization and proton conductivity of titanium phosphate sulfophenylphosphonateSolid State Ionics, 2001
- Zirconium Phosphite (3,3′,5,5′‐Tetramethylbiphenyl)diphosphonate, a Microporous, Layered, Inorganic–Organic PolymerAngewandte Chemie, 1993