Uranyl-catalyzed hydrosilylation of para-quinone methides: access to diarylmethane derivatives
- 25 January 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 19 (7), 1575-1579
- https://doi.org/10.1039/d0ob02455d
Abstract
An efficient and convenient uranyl-catalyzed reductive hydrosilylation reaction of para-quinone methides (p-QMs) was developed by employing silane as the reductant. The hydrosilylation procedure using the UO2(NO3)2·6H2O/Et3SiH catalytic system proceeded smoothly and provided an expedient method for the construction of various diarylmethane derivatives in one step with good to excellent yields.Funding Information
- National Natural Science Foundation of China (21806167)
- National Science Fund for Distinguished Young Scholars (21925603)
- Science Challenge Project (TZ2016004)
- Youth Innovation Promotion Association (2017020)
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