Micron Thick Colloidal Quantum Dot Solids
- 16 June 2020
- journal article
- research article
- Published by American Chemical Society (ACS) in Nano Letters
- Vol. 20 (7), 5284-5291
- https://doi.org/10.1021/acs.nanolett.0c01614
Abstract
Shortwave infrared colloidal quantum dots (SWIR-CQDs) are semiconductors capable of harvesting across the AM1.5G solar spectrum. Today’s SWIR-CQD solar cells rely on spin-coating; however, these films exhibit cracking once thickness exceeds ∼500 nm. We posited that a blade-coating strategy could enable thick QD films. We developed a ligand exchange with an additional resolvation step that enabled the dispersion of SWIR-CQDs. We then engineered a quaternary ink that combined high-viscosity solvents with short QD stabilizing ligands. This ink, blade-coated over a mild heating bed, formed micron-thick SWIR-CQD films. These SWIR-CQD solar cells achieved short-circuit current densities (Jsc) that reach 39 mA cm–2, corresponding to the harvest of 60% of total photons incident under AM1.5G illumination. External quantum efficiency measurements reveal both the first exciton peak and the closest Fabry–Perot resonance peak reaching approximately 80%—this is the highest unbiased EQE reported beyond 1400 nm in a solution-processed semiconductor.Funding Information
- King Abdullah University of Science and Technology (OSR-CRG2018-3737)
- Natural Sciences and Engineering Research Council of Canada (466083)
- QD Solar
- Ontario Research Fund (ORF7)
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