CuSO4/[Cu(NH3)4]SO4-Composite Thermochemical Energy Storage Materials
Open Access
- 11 December 2020
- journal article
- research article
- Published by MDPI AG in Nanomaterials
- Vol. 10 (12), 2485
- https://doi.org/10.3390/nano10122485
Abstract
The thermochemical energy-storage material couple CuSO4/[Cu(NH3)4]SO4 combines full reversibility, application in a medium temperature interval (3 uptake. In order to limit this volume work, as well as enhance the thermal conductivity of the solid material, several composites of anhydrous CuSO4 with inorganic inert support materials were prepared and characterized with regard to their energy storage density, reversibility of the storage reaction, thermal conductivity, and particle morphology. The best thermochemical energy storage properties were obtained for a 10:1 CuSO4-sepiolite composite, combining an attractive energy storage density with slightly improved thermal conductivity and decreased bulk volume work compared to the pure salt.This publication has 31 references indexed in Scilit:
- Material aspects of Solar Salt for sensible heat storageApplied Energy, 2013
- THERMAL ENERGY STORAGE MATERIALS AND SYSTEMSAnnual Review of Heat Transfer, 2012
- Thermal conductivity and permeability of consolidated expanded natural graphite treated with sulphuric acidCarbon, 2011
- Materials used as PCM in thermal energy storage in buildings: A reviewRenewable and Sustainable Energy Reviews, 2011
- A review on long-term sorption solar energy storageRenewable and Sustainable Energy Reviews, 2009
- Solid–gas equilibrium in chemical heat pumps: the NH3–CoCl2 systemApplied Thermal Engineering, 1999
- Review on sustainable thermal energy storage technologies, Part I: heat storage materials and techniquesEnergy Conversion and Management, 1998
- Performance of thermal energy storage unit using CaCl2-NH3system mixed with TiThe Canadian Journal of Chemical Engineering, 1990
- A note on the crystal structure of anhydrous copper sulphateActa Crystallographica, 1961
- Adsorption of Gases in Multimolecular LayersJournal of the American Chemical Society, 1938