Functionalized Boron Nitride-Based Modification Layer as Ion Regulator Toward Stable Lithium Anode at High Current Densities

Abstract

It is difficult to achieve higher energy density with the existing system of lithium (Li)-ion batteries. As a powerful candidate, Li metal batteries are in the renaissance. Unfortunately, the uncontrolled growth process of Li dendrites has limited their actual application. Hence, inhibiting the formation and spread of Li dendrites has become an enormous challenge. Herein, a novel composite separator is developed with functionalized boron nitride nanosheet modification layer as a Li-ion regulator to regulate Li-ion fluxes. The composite separator contains abundant polar groups and nanoscale channels and could achieve uniform electrochemical deposition via the lithiophilic effect and shunting action. Under the synergy influence of the lithiophilic effect and shunting action, Li dendrites are effectively suppressed. As proof, the Li||Li symmetrical cells with composite separators can circulate steadily for a long time under high current densities (10 mA cm^–2, 800 h). Moreover, the LiFePO₄||Li full cells display excellent long cycling performance (82% retention after 800 cycles).