New Search

Export article

Integrated Process for Recovery of Rare-Earth Elements from Lamp Phosphor Waste Using Methanesulfonic Acid


Abstract: End-of-life fluorescent lamps, collected in most countries for their mercury content, are also an interesting source of rare-earth elements. Methanesulfonic acid (MSA) is a cheap and environmentally friendly acid, which is produced in bulk. In this work, an integrated process for the recovery of valuable rare-earth elements via selective separation of three phosphor fractions using MSA as a lixiviant was developed. First, the halophosphate phosphor was selectively leached with pure MSA at room temperature (L/S = 10 L/kg, T = 25 °C, t = 2 h). Second, the valuable YOX phosphor was selectively leached with diluted MSA (5 vol %; L/S = 10 L/kg; t = 2 h, T = 80 °C). Finally, the remaining LAP phosphor was leached with pure MSA (T = 180 °C, L/S = 15 L/kg, t = 6 h). This highly selective sequential leaching process is based on the combination of hydro- and solvometallurgy. The calcium-rich pregnant leach solution was purified via vacuum distillation. The yttrium-rich and the lanthanum-rich pregnant leach solutions were purified via solvent extraction with bis(2-ethylhexyl)phosphoric acid, followed by stripping with oxalic acid. A conceptual flowsheet for the developed closed-loop recycling process is presented.
Keywords: phosphor / Methanesulfonic / purified / pregnant / lamps / rich / L/S / L/kg / MSA / leached

Scifeed alert for new publications

Never miss any articles matching your research from any publisher
  • Get alerts for new papers matching your research
  • Find out the new papers from selected authors
  • Updated daily for 49'000+ journals and 6000+ publishers
  • Define your Scifeed now

Share this article

Click here to see the statistics on "Industrial & Engineering Chemistry Research" .
References (22)
    Back to Top Top