Assembly of 12-Tungstovanadate-Templated Nanocage and Nanocomposites with Single-Walled Carbon Nanotubes as Anodes in Lithium-Ion Batteries
- 6 July 2020
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 59 (13), 9244-9251
- https://doi.org/10.1021/acs.inorgchem.0c01150
Abstract
A new 12-tungstovanadate-templated 3D nanocage framework, Ag-10(mu(4)-ttz)(4)(H2O)(4)(VW12O40) (VW12@MOCF), was designed based on a "molecular library", hydrothermally synthesized, structurally characterized, and explored as anode material for lithium-ion batteries (LIBs). Combination of the structural superiority of VW12@MOCF with the good electrical conductivity of the single-walled carbon nanotubes (SWNTs) renders the VW12@MOCF/SWNT-2 nanocomposite reasonable electrochemical performance and stability as anode materials of LIBs. The successful cooperative fabrication of nanocages and polyoxometalate (POMs) must initiate extensive research interests.Funding Information
- National Natural Science Foundation of China (21901139)
- Basic Research Project on Basic Scientific Research Operating Costs of Provincial Colleges and Universities in Heilongjiang Province (2018-KYYWF-0089)
- Talent Culturing Plan for Leading Disciplines of University of Shandong Province
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