Triiron clusters derived from dinuclear complexes related to the active site of [Fe–Fe] hydrogenases: steric effect of the dithiolate bridge on redox properties, a DFT analysis
- 6 February 2021
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Inorganic Chemistry Frontiers
- Vol. 8 (15), 3659-3674
- https://doi.org/10.1039/d1qi00006c
Abstract
CV and DFT calculations reveal that electrochemical behaviours of triiron clusters [Fe3(CO)5(κ2-dppe)(μ-pdtR2)(μ-pdt)] depend on the nature of the dithiolate bridge.Keywords
Funding Information
- Centre National de la Recherche Scientifique
- Université de Bretagne Occidentale
- Università degli Studi di Milano-Bicocca
- Région Bretagne
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