Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions
- 2 March 2021
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 50 (8), 5201-5242
- https://doi.org/10.1039/d0cs01341b
Abstract
N2is fixed as NH3industrially by the Haber–Bosch process under harsh conditions, whereas biological nitrogen fixation is achieved under ambient conditions, which has prompted development of alternative methods to fix N2catalyzed by transition metal molecular complexes.Keywords
This publication has 510 references indexed in Scilit:
- N2 Functionalization at Iron MetallaboratranesJournal of the American Chemical Society, 2011
- Thermochemistry of Proton-Coupled Electron Transfer Reagents and its ImplicationsChemical Reviews, 2010
- Characterization of Isolated Nitrogenase FeVcoJournal of the American Chemical Society, 2010
- Synthesis of DiamidoPyrrolyl Molybdenum Complexes Relevant to Reduction of Dinitrogen to AmmoniaInorganic Chemistry, 2010
- Access to Well‐Defined Ruthenium(I) and Osmium(I) MetalloradicalsAngewandte Chemie, 2010
- Formation of {[HIPTN3N]Mo(III)H}−by Heterolytic Cleavage of H2as Established by EPR and ENDOR SpectroscopyInorganic Chemistry, 2009
- Theory of Proton-Coupled Electron Transfer in Energy Conversion ProcessesAccounts of Chemical Research, 2009
- Molybdenum Triamidoamine Systems. Reactions Involving Dihydrogen Relevant to Catalytic Reduction of DinitrogenInorganic Chemistry, 2009
- Synthesis of Molybdenum Complexes that Contain “Hybrid” Triamidoamine Ligands, [(Hexaisopropylterphenyl-NCH2CH2)2NCH2CH2N-aryl]3-, and Studies Relevant to Catalytic Reduction of DinitrogenInorganic Chemistry, 2006
- Synthesis of [(HIPTNCH2CH2)3N]V Compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an Evaluation of Vanadium for the Reduction of Dinitrogen to AmmoniaInorganic Chemistry, 2006