Bifunctional Atomically Dispersed Mo–N2/C Nanosheets Boost Lithium Sulfide Deposition/Decomposition for Stable Lithium–Sulfur Batteries
- 22 July 2020
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Nano
- Vol. 14 (8), 10115-10126
- https://doi.org/10.1021/acsnano.0c03325
Abstract
The sluggish kinetics of lithium polysulfides (LiPS) transformation is recognized as the main obstacle against the practical applications of Lithium sulfur (Li-S) battery. Inspired by molybdoenzymes in biological catalysis with stable Mo-S bonds, porous Mo-N-C nanosheets with atomically dispersed Mo-N2/C sites are developed as a cathode to boost the LiPS adsorption and conversion for Li-S battery. Thanks to its high intrinsic activity and unique Mo-N coordination structure, the rate capability and cycling stability of S/Mo-N-C are greatly improved compared with S/N-C due to the accelerated kinetics and suppressed shuttle effect. The S/Mo-N-C delivers a high reversible capacity of 743.9 mAh g-1 at 5 C rate and an extremely low capacity decay rate of 0.018% per cycle after 550 cycles at 2 C rate, outperforming most of the reported electrodes. Density functional theory (DFT) calculations suggest that the Mo-N2/C sites can bifunctionally lower the activation energy for Li2S4 to Li2S conversion and the decomposition barrier of Li2S, accounting for its inherently high activity towards LiPS transformation.Keywords
Funding Information
- National Materials Genome Project (2016YFB0700600)
- Huazhong University of Science and Technology (2019ygscxcy031)
- National Natural Science Foundation of China (21972051)
- Division of Materials Research (DMR1828019)
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