Chiral Plasmonic Nanoparticle Assisted Raman Enantioselective Recognition
- 16 June 2020
- journal article
- research article
- Published by American Chemical Society (ACS) in Analytical Chemistry
- Vol. 92 (12), 8015-8020
- https://doi.org/10.1021/acs.analchem.0c01311
Abstract
Au nanoparticles (NPs) labeled with the handedness tag of "D-" or "L-", which were detached from inorganic chiral silica, showed both intrinsic chirality and surface enhanced Raman scattering (SERS) activity. In the presence of these chiral Au substrates, it was found that the enantiomer of cystine with the same handedness tag of Au NPs would show stronger Raman scattering signal intensities than those of the enantiomer with the opposite tag, where the differences could be over three times. Consequently, this work afforded a novel enantioselective recognition method on ordinary Raman spectroscopy by using chiral plasmonic metallic nanomaterials.Funding Information
- Japan Society for the Promotion of Science (19H02767, JP16H06515)
- National Natural Science Foundation of China (21475088)
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