Synthesis of Zn-Li Bimetallic Compound and Its Catalytic Application in Hydroboration of Isocyanate
- 1 January 2021
- journal article
- research article
- Published by Shanghai Institute of Organic Chemistry in Chinese Journal of Organic Chemistry
- Vol. 41 (1), 357-363
- https://doi.org/10.6023/cjoc202006027
Abstract
There are very few reports on the isocyanate hydroboration. So far, the Zn-catalyzed hydroboration of isocyanate has not been reported. The synthesis of a novel asymmetric beta-diketiminate Zn-Li bimetallic compound and its application as a highly efficient catalyst in the hydroboration of various isocyanates with HBpin in high yields are reported. The preliminary mechanism of hydroboration reaction has been explored.Keywords
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